column 7 of the hazardous materials table column 7 of the hazardous materials table

Column 7: Special Provisions - Specifies codes for special provisions applicable to some hazardous materials. Tables 1, 2, and 3 follow: 1 Flexible plastic (51H) Large Packagings are only authorized for use with flexible inner packagings. b. After filling, each glass inner packaging must be determined to be leak-tight by placing the glass inner packaging in a hot water bath at a temperature and for a period of time sufficient to ensure that an internal pressure equal to the vapor pressure of ethylene oxide at 55 C is achieved. 52 This entry may only be used for substances that are too insensitive for acceptance into Class 1 (explosive) when tested in accordance with Test Series 2 in the UN Manual of Tests and Criteria, Part I (incorporated by reference; see 171.7 of this subchapter). On the basis of the results of suitable burning rate tests, and taking into account the standard tests in the UN Manual of Tests and Criteria, Part III, subsection 33.2.1 (IBR, see 171.7 of this subchapter), nitrocellulose membrane filters in the form in which they are to be transported that do not meet the criteria for a Division 4.1 material are not subject to the requirements of this subchapter. The Meaning of the Symbols in Column 7 of the Hazardous Materials Table Testing must be conducted on at least three packages as prepared for transport. Ammonia solutions may be transported in rigid or composite plastic IBCs (31H1, 31H2 and 31HZ1) that have successfully passed, without leakage or permanent deformation, the hydrostatic test specified in. Thickness of stainless steel for tank shell and heads for cargo tanks and portable tanks must be the greater of 7.62 mm (0.300 inch) or the thickness required for a tank with a design pressure at least equal to 1.5 times the vapor pressure of the lading at 46 C (115 F). 16 This description applies to smokeless powder and other solid propellants that are used as powder for small arms and have been classed as Division 1.3C, 1.4C and Division 4.1 in accordance with 173.56 of this subchapter. Flammable components are flammable liquids and liquid mixtures, flammable solids and solid mixtures or flammable gases and gas mixtures meeting the following criteria: (1) A flammable liquid is a liquid having a flashpoint of not more than 93 C (200 F); (2) A flammable solid is a solid that meets the criteria in 173.124 of this subchapter; or. 157 When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.151(b)(1)(i) of this subchapter for inner packagings may be increased to 5 kg (11 pounds). B70 If DOT 103ANW tank car tank is used: All cast metal in contact with the lading must have 96.7 percent nickel content; and the lading must be anhydrous and free from any impurities. If chemical stabilization becomes ineffective at lower temperatures within the anticipated duration of transport, temperature control is required and is forbidden by aircraft. Kits that are carried on board transport vehicles for first aid or operating purposes are not subject to the requirements of this subchapter. B44 All parts of valves and safety relief devices in contact with lading must be of a material which will not cause formation of acetylides. Prior to repacking into the life-saving appliance, an installed inflation cylinder must successfully meet and pass all inspection and test criteria and standards of the raft manufacturer and the vessel Flag State requirements for cylinders installed as part of life-saving appliances, self-inflating (UN2990) used on marine vessels. A7 Steel packagings must be corrosion-resistant or have protection against corrosion. ; and. A2 Single packagings are not permitted on aircraft. These provisions apply only to transportation by rail. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. e. When offered for transport in an ammonia dispenser, the receptacles shall be connected to the dispenser in such a way that the assembly is guaranteed to have the same strength as a single receptacle. 420 This entry does not apply to manufactured articles (such as table tennis balls). 384 For green graphite electrodes and shapes that are large single component solid objects not subject to shifting, transport in open rail flat cars, open bed motor vehicles, and intermodal containers is also authorized. Nickel-carbon asymmetric capacitors containing Class 8 alkaline electrolytes must be transported as UN2795, Batteries, wet, filled with alkali, electric storage. A54 Irrespective of the quantity limits in Column 9B of the 172.101 table, a lithium battery, including a lithium battery packed with, or contained in, equipment that otherwise meets the applicable requirements of 173.185, may have a mass exceeding 35 kg if approved by the Associate Administrator prior to shipment. B49 Tanks equipped with interior heater coils are not authorized. There must be no hazardous effects outside the package such as disruption of the package, metal fragments or a receptacle which passes through the packaging. (ii) The following is a list of the portable tank special provisions: TP1 The maximum degree of filling must not exceed the degree of filling determined by the following: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. 49 U.S.C. 172-123, 55 FR 52582, Dec. 21, 1990]. Filling limits must be in accordance with portable tank special provision TP3. In making this determination factors to be taken into consideration include, but are not limited to, the capacity and geometry of the packaging and the effect of any insulation present, the temperature of the material when offered for transport, the duration of the journey, and the ambient temperature conditions typically encountered in the journey (considering also the season of year), the effectiveness and other properties of the stabilizer employed, applicable operational controls imposed by regulation (e.g., requirements to protect from sources of heat, including other cargo carried at a temperature above ambient) and any other relevant factors. When a special provision specifies packaging or packaging requirements -, (1) The special provision is in addition to the standard requirements for all packagings prescribed in 173.24 of this subchapter and any other applicable packaging requirements in subparts A and B of part 173 of this subchapter; and. result, it may not include the most recent changes applied to the CFR. B35 Tank cars containing hydrogen cyanide may be alternatively marked Hydrocyanic acid, liquefied if otherwise conforming to marking requirements in subpart D of this part. TP47 The 2.5 year internal examination may be waived or substituted by other test methods or inspection procedures specified by the competent authority or its authorized body, provided that the portable tank is dedicated to the transport of the organometallic substances to which this tank special provision is assigned. 149 When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to 5 L (1.3 gallons). You can A82 The quantity limits in columns (9A) and (9B) do not apply to human or animal body parts, whole organs or whole bodies known to contain or suspected of containing an infectious substance. The tank car specification may be marked to indicate a test pressure of 13.79 Bar (200 psig). 369 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN 2978. If a tank car tank is equipped with a non-reclosing pressure relief device, the rupture disc must be perforated with a 3.2 mm (0.13 inch) diameter hole. This content is from the eCFR and may include recent changes applied to the CFR. Except as provided in 173.185(c)(3) of this subchapter, the package must be marked UN 3091 Lithium metal batteries packed with equipment, or UN 3481 Lithium ion batteries packed with equipment, as appropriate. The requirements of 173.24(g)(1) and 173.27(c) do not apply. (4) A code containing the letters IB or IP refers to a special provision that applies only to transportation in IBCs. (You can unsubscribe anytime), Learn More About USDOT/HazMat Transportation, generalpackaging requirements of173.24, Frequently Asked Questions Regarding the Regulations of the Resource Conservation and Recovery Act. A14 This material is not authorized to be transported as a limited quantity or consumer commodity in accordance with 173.306 of this subchapter when transported aboard an aircraft. Please do not provide confidential You can learn more about the process (5) A code containing the letter N refers to a special provision which applies only to non-bulk packaging requirements. B81 Venting and pressure relief devices for tank car tanks and cargo tanks must be approved by the Associate Administrator. (i) These provisions apply to the transportation of hazardous materials in IM and UN Specification portable tanks. 163 Substances must satisfactorily pass Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18 (IBR, see 171.7 of this subchapter). (6) The rate of oxygen release from the outer packaging does not exceed 15 mL per hour. TP38 Each portable tank must be insulated with an insulating material so that the overall thermal conductance at 15.5 C (60 F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. b. A61 a. Outage must be at least 5 percent at 98 C (208 F). Shipments must be made by private, leased or contract carrier vehicles under exclusive use of the offeror. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter. (b) Preparation for transport. Specifically, you seek clarification on the implementation of special provision IP15which is listed in Column 7 of the 172.101 Hazardous Materials Table (HMT)as it applies when this material is packaged in a composite intermediate bulk container (IBC) with a rigid inner receptacle. 64 The group of alkali metals includes lithium, sodium, potassium, rubidium, and caesium. (ii) One bottle for every two hours of production, or for every 2,500 bottles produced, must be tested by dropping a bottle filled to 98 percent capacity with water from a height of 1.2 meters (3.9 feet) onto solid concrete directly on the closure. b. Examples of equipment are lawnmowers, cleaning machines, or model boats and model aircraft. Component cells of the battery must be of a type proved to meet the respective testing requirements of the Manual of Tests and Criteria, part III, subsection 38.3 (IBR, see 171.7 of this subchapter). c. Completed neutron radiation detection systems containing detectors meeting the conditions of paragraph a of this special provision must be transported as follows: (1) The detectors must be contained in a strong sealed outer casing; (2) The casing must contain include sufficient absorbent or adsorbent material to absorb or adsorb the entire gas contents; (3) The completed system must be packed in strong outer packagings capable of withstanding a 1.8 meter (5.9 feet) drop test without leakage unless a system's outer casing affords equivalent protection. Packagings of other material with a small amount of metal, for example metal closures or other metal fittings such as those mentioned in part 178 of this subchapter, are not considered metal packagings. The standards for transporting a single bulk hazardous material for blasting by cargo tank motor vehicles (CTMV); and. Column 1 specifies the T Code. 351 Ammonium chlorate, ammonium chlorate aqueous solutions, and mixtures of a chlorate with an ammonium salt are forbidden for transport. N12 Plastic packagings are not authorized. When Column 7 refers to a special provision for a hazardous material, the meaning and requirements of that special provision are as set forth in 172.102 of this subpart. The following tables list, and set forth the requirements of, the special provisions referred to in column 7 of the 172.101 table. A100 Lithium ion cells and batteries must be offered for transport at a state of charge not exceeding 30 percent of their rated capacity. b. Lithium batteries conforming to paragraph a. of this special provision must be assigned to UN Nos. A hypochlorite solution, UN1791, is a Class 8 corrosive material. Use of these proper shipping names for domestic shipments may be made only under a DOT special permit, as defined in, and in accordance with the requirements of subpart B of part 107 of this subchapter. FAQ: What are Special Provisions in the USDOT/PHMSA Hazardous Materials They must be classified in accordance with the procedure as set out in the Manual of Tests and Criteria, part III, section 39 (IBR, see 171.7 of this subchapter). The coal tar pitch compound must be in a solid mass during transportation. "Published Edition". 23 This material may be transported under the provisions of Division 4.1 only if it is so packed that the percentage of diluent will not fall below that stated in the shipping description at any time during transport. Bulk outer packagings must be liquid tight through design or by the use of lining materials. B3 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks and DOT 57 portable tanks are not authorized. (iii) A copy of the test results must be kept on file at each facility where packagings are offered for transportation, and must be made available to a representative of the Department upon request. 237 Batteries, dry, containing potassium hydroxide solid, electric storage must be prepared and packaged in accordance with the requirements of 173.159(a) and (c). The total weight of the explosive contents of the shaped charges assembled in the guns does not exceed 90.5 kg (200 pounds) per vehicle; and. Learn more about the eCFR, its status, and the editorial process. N92 Notwithstanding the provisions of 173.24(g) of this subchapter, packagings shall be designed and constructed to permit the release of gas or vapor to prevent a build-up of pressure that could rupture the packagings in the event of loss of stabilization. This is an automated process for meet the venting requirements in 173.24(g) or (2.) The HMT provides the basic information necessary to ship a hazardous material safely. Packages containing mixtures with not less than 90% by mass, of phlegmatizer need not bear a POISON subsidiary risk label. When there is an entry in this column, refer to Section 172.102 of the federal regulations for specific information. c. A composite packaging 6PG2 (glass, porcelain or stoneware receptacles within a fiberboard box). Each special provision is indicated using a numeric or alphanumeric code. Energy storage capacity means the energy held by a capacitor, as calculated using the nominal voltage and capacitance. The proper shipping name Paint related material may be used for consignments of packages containing Paint and Paint related material in the same package; b. B115 Rail cars, highway trailers, roll-on/roll-off bins, or other non-specification bulk packagings are authorized. Examples of such vehicles are cars, motorcycles, trucks, locomotives, scooters, three- and four-wheeled vehicles or motorcycles, lawn tractors, self-propelled farming and construction equipment, boats, and aircraft. (iii) T50 When portable tank instruction T50 is indicated in Column (7) of the 172.101 Hazardous Materials Table, the applicable liquefied compressed gas and chemical under pressure descriptions are authorized to be transported in portable tanks in accordance with the requirements of 173.313 of this subchapter. 5. Authorized specification bulk outer packagings are UN11G fiberboard intermediate bulk containers (IBC) and UN13H4 woven plastic, coated and with liner flexible intermediate bulk containers (FIBCs) meeting the Packing Group II performance level and lined with a plastic liner of at least 6 mil thickness. formatting. If appropriate, a package containing this material must conform to the additional labeling requirements of 172.402 of this subchapter. Non-specification bulk bins are authorized. Note 1: Based on maximum lading pressure of 1 psig at top of cargo tank. not more than 0.1 mL/hour per 30 mL inner packaging at 20 C (68 F) produced from gradual decomposition. The examination and testing of each lighter design must be performed by a person authorized by the Associate Administrator under the provisions of subpart E of part 107 of this chapter, as specified in 173.308(a)(4). View the most recent official publication: These links go to the official, published CFR, which is updated annually. 43 The membrane filters, including paper separators and coating or backing materials, that are present in transport, must not be able to propagate a detonation as tested by one of the tests described in the UN Manual of Tests and Criteria, Part I, Test series 1(a) (IBR, see 171.7 of this subchapter). a. B14 Each bulk packaging, except a tank car or a multi-unit-tank car tank, must be insulated with an insulating material so that the overall thermal conductance at 15.5 C (60 F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. TP13 Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. 148 For domestic transportation, this entry directs to 173.66 for: a. 357 A bulk packaging that emits hydrogen sulfide in sufficient concentration that vapors evolved from the crude oil can present an inhalation hazard must be marked as specified in 172.327 of this part. Net weight of contents in wooden boxes, barrels or kegs may not exceed 45 kg (99 pounds). Those "other methods" for determining authorized packaging are identified at 173.24 (c) (1) (ii). Column 5 references applicable requirements for bottom openings in part 178 of this subchapter. Other inorganic nitrate salts may replace part of the ammonium nitrate. If you have comments or suggestions on how to improve the www.ecfr.gov website or have questions about using www.ecfr.gov, please choose the 'Website Feedback' button below. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the subpart E (labeling) requirements of this part when offered for transportation by motor vehicle, rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned in 173.62 of this subchapter, in conformance with the following conditions: a. Batteries and battery-powered device(s) containing batteries must be prepared and packaged for transport in a manner to prevent: (2) Short circuits, including but not limited to the following methods: (i) Packaging each battery or each battery-powered device when practicable, in fully enclosed inner packagings made of non-conductive material; (ii) Separating or packaging batteries in a manner to prevent contact with other batteries, devices or conductive materials (e.g., metal) in the packagings; or, (iii) Ensuring exposed terminals or connectors are protected with non-conductive caps, non-conductive tape, or by other appropriate means; and. 162 This material may be transported under the provisions of Division 4.1 only if it is packed so that at no time during transport will the percentage of diluent fall below the percentage that is stated in the shipping description. The total mass of lithium batteries contained in any package must not exceed the quantity limits in columns (9A) and (9B) for passenger aircraft or cargo aircraft, as applicable; b. Amdt. B2 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized. This entry may not be used for solids containing a Packing Group I liquid. This content is from the eCFR and is authoritative but unofficial. 111 Explosive substances of Division 1.1 Compatibility Group A (1.1A) are forbidden for transportation if dry or not desensitized, unless incorporated in a device. authorized by name in the Hazardous Materials Table or have been specifically authorized by name either in the Section 172.101 Hazardous Materials Table or have been assigned a shipping name and hazard class by the Associate Administrator for Hazardous Materials Safety. 176 This entry must be used for formaldehyde solutions containing methanol as a stabilizer. Examples of such vehicles are electrically-powered cars, motorcycles, scooters, three- and four-wheeled vehicles or motorcycles, trucks, locomotives, bicycles (pedal cycles with an electric motor) and other vehicles of this type (e.g., self-balancing vehicles or vehicles not equipped with at least one seating position), lawn tractors, self-propelled farming and construction equipment, boats, aircraft, wheelchairs and other mobility aids. The table below gives the various types of Lead alloy solders. Each tank car must have a reclosing pressure relief device having a start-to-discharge pressure of 10.34 Bar (150 psig). Comments or questions about document content can not be answered by OFR staff. Data collection and handling. Lead compounds that have a solubility of 5% or less in accordance with this special provision are not subject to the requirements of this subchapter that pertain to Marine Pollutants. No outage is required for helium. The map below, compiled from data provided by the Federal Emergency Management Agency (FEMA), is the most accurate nuclear attack map and fallout demonstration available for 2023: (Image courtesy of FEMA and Halcyon Maps) The fallout would rapidly spread, turning targeted cities into whole affected regions.